Supramolecular Gelation of Rigid Triangular Macrocycles through Rings of Multiple C–H···O Interactions Acting Cooperatively

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Selective binding of hydrogen chloride and its trapping through supramolecular gelation.

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Abstract In order to develop a new class of macro cyclic receptors with a unique shape and set of functional groups the synthesis of novel aromatic dialdehydes I and II using mild conditions oxidation (Mn02) and dibromination-dilithiation methodology has been carried out. Conditions of the oxidation step have been optimised. The study of the reactivity of the dicarboxyaldehydes I and II, in the...

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ژورنال

عنوان ژورنال: The Journal of Organic Chemistry

سال: 2016

ISSN: 0022-3263,1520-6904

DOI: 10.1021/acs.joc.6b00281